Journal article
Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine.
- Abstract:
- Reactions of the 2-phosphaethynolate anion (PCO(-), 1) with ammonium salts quantitatively yielded phosphinecarboxamide (PH2C(O)NH2, 2). The molecular structure and chemical properties of 2 were studied by single-crystal X-ray diffraction and multielement NMR spectroscopy. This phosphorus-containing analogue of urea is a rare example of an air-stable primary phosphine.
- Publication status:
- Published
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Authors
- Journal:
- Journal of the American Chemical Society More from this journal
- Volume:
- 135
- Issue:
- 51
- Pages:
- 19131-19134
- Publication date:
- 2013-12-01
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Language:
-
English
- Pubs id:
-
pubs:441560
- UUID:
-
uuid:a5f07975-36f3-45a0-818c-b4046977865d
- Local pid:
-
pubs:441560
- Source identifiers:
-
441560
- Deposit date:
-
2013-12-10
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- Copyright date:
- 2013
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