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Phosphinecarboxamide: a phosphorus-containing analogue of urea and stable primary phosphine.

Abstract:
Reactions of the 2-phosphaethynolate anion (PCO(-), 1) with ammonium salts quantitatively yielded phosphinecarboxamide (PH2C(O)NH2, 2). The molecular structure and chemical properties of 2 were studied by single-crystal X-ray diffraction and multielement NMR spectroscopy. This phosphorus-containing analogue of urea is a rare example of an air-stable primary phosphine.
Publication status:
Published

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Publisher copy:
10.1021/ja4115693

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
Journal of the American Chemical Society More from this journal
Volume:
135
Issue:
51
Pages:
19131-19134
Publication date:
2013-12-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863


Language:
English
Pubs id:
pubs:441560
UUID:
uuid:a5f07975-36f3-45a0-818c-b4046977865d
Local pid:
pubs:441560
Source identifiers:
441560
Deposit date:
2013-12-10

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