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Complexes of a gallium heterocycle with transition metal dicyclopentadienyl and cyclopentadienylcarbonyl fragments, and with a dialkylmanganese compound.

Abstract:

The reactivity of several transition metal half sandwich complexes towards an anionic gallium(I) heterocyclic complex, [K(tmeda)][Ga{[N(Ar)C(H)]2}](Ar = C6H3Pri2-2,6), has been investigated. This has led to the anionic half sandwich complexes, [K(tmeda)][(C5H4R)M(CO)n[Ga{[N(Ar)C(H)]2}]](M = V, R = H, n= 3; M = Mn, R = Me, n= 2; M = Co, R = H, n= 1), which crystallographic studies show to form dimers (M = Mn and Co) or a polymer (M = V) through bridging potassium cations. The metal-gallium bon...

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Publication status:
Published

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Publisher copy:
10.1039/b604640a

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
27
Pages:
3313-3320
Publication date:
2006-07-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:a5a710fe-2bb0-4be6-a25a-efb94865b645
Source identifiers:
46042
Local pid:
pubs:46042
Language:
English

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