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NEW CONSTRAINTS FOR NORMAL-MODE ANALYSIS OF INELASTIC NEUTRON-SCATTERING SPECTRA - APPLICATION TO THE HF2- ION

Abstract:
Intensities of the overtone and combination bands of molecular vibrational INS spectroscopy have been used, for the first time, to constrain the normal coordinate refinement of a spectrum. This was performed on a new high resolution spectrum of NaHF2. The LO-TO splittings suggested previously by optical work are now clearly observed. The possibility of further constraining refinements, by using the momentum transfer variation of band intensities, is presented. © 1987 Springer-Verlag.
Publication status:
Published

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Publisher copy:
10.1007/BF01560611

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Publisher:
Springer-Verlag
Journal:
ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER More from this journal
Volume:
69
Issue:
1
Pages:
63-67
Publication date:
1987-01-01
DOI:
EISSN:
1434-6036
ISSN:
0722-3277


Language:
English
Pubs id:
pubs:121749
UUID:
uuid:a4eec722-0668-4f6a-98dd-1ccb8bf50f01
Local pid:
pubs:121749
Source identifiers:
121749
Deposit date:
2012-12-19

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