Journal article
The effect of alumina on phase transformations at the 660-kilometer discontinuity from Fe-Mg partitioning experiments
- Abstract:
- Experimental data on the partitioning of Fe and Mg between coexisting silicate perovskite, magnesiowustite, and γ-(Mg,Fe)2SiO4 demonstrate that Fe substitution in perovskite is strongly coupled to Al2O3 concentration. In Al2O3-free compositions, perovskite has a low Fe/(Fe+Mg) ratio: for a bulk Fe/(Fe+Mg) of 0.11, perovskite has a value close to 0.04, whereas magnesiowustite has a ratio near 0.17. In peridotitic mantle, however, where the perovskite should contain 4 to 5 weight percent Al2O3, it has essentially the same Fe/(Fe+Mg) ratio as coexisting magnesiowustite. Under lower mantle conditions, therefore, perovskite and magnesiowustite should, in peridotite, each have an Fe/(Fe+Mg) ratio close to 0.11.
- Publication status:
- Published
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Authors
- Journal:
- SCIENCE More from this journal
- Volume:
- 273
- Issue:
- 5281
- Pages:
- 1522-1524
- Publication date:
- 1996-09-13
- DOI:
- EISSN:
-
1095-9203
- ISSN:
-
0036-8075
- Language:
-
English
- Pubs id:
-
pubs:163818
- UUID:
-
uuid:a3a33fb4-bbb9-4d89-b80d-cf35a1778aac
- Local pid:
-
pubs:163818
- Source identifiers:
-
163818
- Deposit date:
-
2012-12-19
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- Copyright date:
- 1996
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