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A reversible, unidirectional molecular rotary motor driven by chemical energy.

Abstract:
With the long-term goal of producing nanometer-scale machines, we describe here the unidirectional rotary motion of a synthetic molecular structure fueled by chemical conversions. The basis of the rotation is the movement of a phenyl rotor relative to a naphthyl stator about a single bond axle. The sense of rotation is governed by the choice of chemical reagents that power the motor through four chemically distinct stations. Within the stations, the rotor is held in place by structural features that limit the extent of the rotor's Brownian motion relative to the stator.
Publication status:
Published

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Publisher copy:
10.1126/science.1117090

Authors



Journal:
Science (New York, N.Y.) More from this journal
Volume:
310
Issue:
5745
Pages:
80-82
Publication date:
2005-10-01
DOI:
EISSN:
1095-9203
ISSN:
0036-8075


Language:
English
Pubs id:
pubs:117859
UUID:
uuid:a36a7d5b-69db-45cd-adce-af4fd09ab4f0
Local pid:
pubs:117859
Source identifiers:
117859
Deposit date:
2012-12-19

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