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The even-handed approach: strategies for the deployment of racemic chiral catalysts.

Abstract:

Asymmetric catalysis is predominantly associated with the use of enantiomerically pure chiral ligands and catalysts. Although racemic chiral catalysts have been employed quite extensively in polymerization, their utility in mainstream organic synthesis and catalyst development has arguably been rather overlooked. This Minireview collates various themes for the strategic application of racemic ligands and catalysts, ranging from the estimation of selectivity and determination of enantiomeric e...

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Publication status:
Published

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Publisher copy:
10.1002/anie.201106836

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Journal:
Angewandte Chemie (International ed. in English)
Volume:
51
Issue:
7
Pages:
1526-1533
Publication date:
2012-02-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:a31e1dd2-4ec2-4eca-a516-24f7e0cfcaca
Source identifiers:
237670
Local pid:
pubs:237670

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