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Dimensional reduction by geometrical frustration in a cubic antiferromagnet composed of tetrahedral clusters

Abstract:
Dimensionality is a critical factor in determining the properties of solids and is an apparent built-in character of the crystal structure. However, it can be an emergent and tunable property in geometrically frustrated spin systems. Here, we study the spin dynamics of the tetrahedral cluster antiferromagnet, pharmacosiderite, via muon spin resonance and neutron scattering. We find that the spin correlation exhibits a two-dimensional characteristic despite the isotropic connectivity of tetrahedral clusters made of spin 5/2 Fe3+ ions in the three-dimensional cubic crystal, which we ascribe to two-dimensionalisation by geometrical frustration based on spin wave calculations. Moreover, we suggest that even one-dimensionalisation occurs in the decoupled layers, generating low-energy and one-dimensional excitation modes, causing large spin fluctuation in the classical spin system. Pharmacosiderite facilitates studying the emergence of low-dimensionality and manipulating anisotropic responses arising from the dimensionality using an external magnetic field.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1038/s41467-021-24636-1

Authors


More by this author
Institution:
University of Oxford
Department:
PHYSICS
Sub department:
Condensed Matter Physics
Role:
Author


Publisher:
Nature Research
Journal:
Nature Communications More from this journal
Volume:
12
Issue:
1
Article number:
4382
Publication date:
2021-07-19
Acceptance date:
2021-06-28
DOI:
EISSN:
2041-1723


Language:
English
Keywords:
Pubs id:
1186929
Local pid:
pubs:1186929
Deposit date:
2021-07-19

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