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The lipid linked oligosaccharide polymerase Wzy and its regulating co-polymerase, Wzz, from enterobacterial common antigen biosynthesis form a complex

Abstract:
The enterobacterial common antigen (ECA) is a carbohydrate polymer that is associated with the cell envelope in the Enterobacteriaceae . ECA contains a repeating trisaccharide which is polymerized by WzyE, a member of the Wzy membrane protein polymerase superfamily. WzyE activity is regulated by a membrane protein polysaccharide co-polymerase, WzzE. Förster resonance energy transfer experiments demonstrate that WzyE and WzzE from Pectobacterium atrosepticum form a complex in vivo , and immunoblotting and cryo-electron microscopy (cryo-EM) analysis confirm a defined stoichiometry of approximately eight WzzE to one WzyE. Low-resolution cryo-EM reconstructions of the complex, aided by an antibody recognizing the C-terminus of WzyE, reveals WzyE sits in the central membrane lumen formed by the octameric arrangement of the transmembrane helices of WzzE. The pairing of Wzy and Wzz is found in polymerization systems for other bacterial polymers, including lipopolysaccharide O-antigens and capsular polysaccharides. The data provide new structural insight into a conserved mechanism for regulating polysaccharide chain length in bacteria.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1098/rsob.220373

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Institution:
University of Oxford
Role:
Author
ORCID:
0000-0002-1419-9378
More by this author
Institution:
University of Oxford
Role:
Author
ORCID:
0000-0003-2546-3426


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Funder identifier:
https://ror.org/029chgv08
Grant:
100209/Z/12/Z
More from this funder
Funder identifier:
https://ror.org/05etxs293
Grant:
EM16637-1
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Funder identifier:
https://ror.org/03x94j517
Grant:
MC_UU_12014/7
More from this funder
Funder identifier:
https://ror.org/01gavpb45
Grant:
FDN-2016-148364
More from this funder
Funder identifier:
10.13039/501100000268


Publisher:
The Royal Society
Journal:
Open Biology More from this journal
Volume:
13
Issue:
3
Pages:
220373
Article number:
220373
Publication date:
2023-03-22
Acceptance date:
2023-02-27
DOI:
EISSN:
2046-2441
ISSN:
2046-2441


Language:
English
Keywords:
Pubs id:
1333940
Local pid:
pubs:1333940
Source identifiers:
3794556
Deposit date:
2026-02-25
ARK identifier:
This ORA record was generated from metadata provided by an external service. It has not been edited by the ORA Team.

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