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The wall-jet ring-disc electrode: The measurement of homogeneous rate constants from steady state ring currents

Abstract:
The wall-jet ring-disc electrode is shown to provide a convenient means determining homogeneous rate constants by means of ring current measurements as a function of disc currents and electrolyte flow rates. Theory is provided for the analysis of such “collection efficiency” experiments and applied to the specific case of the bromination of anisole, where good agreement with experiment is found. Advantages with respect to the rotating ring-disc electrode are pointed out.
Publication status:
Published

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Publisher copy:
10.1002/elan.1140030707

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Institution:
University of Oxford
Role:
Author
More by this author
Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author


Journal:
Electroanalysis More from this journal
Volume:
3
Issue:
7
Pages:
631-636
Publication date:
1991-08-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397


Pubs id:
pubs:43688
UUID:
uuid:9bf784ca-d69f-4ee7-b280-5df9df7d975f
Local pid:
pubs:43688
Source identifiers:
43688
Deposit date:
2012-12-19
ARK identifier:

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