Journal article

Chelation-controlled intermolecular hydroacylation: direct addition of alkyl aldehydes to functionalized alkenes.

Abstract:: The pendant methylsulfanyl group of aldehyde 1 provides chelation stabilization (see 3), thus allowing direct hydroacylation of functionalized electron-poor alkenes 2 in good yields under mild conditions. Electron-deficient alkynes can also be used as substrates. R = ester, arnide, imide, sulfone; dppe = 1,2-bis(diphenylphosphanyl)ethane.

Publication status:: Published

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APA Style

Willis, M., McNally, S., & Beswick, P. (2004). Chelation-controlled intermolecular hydroacylation: direct addition of alkyl aldehydes to functionalized alkenes. Angewandte Chemie (International Ed. in English), 43(3), 340–343.

MLA Style

Willis, M., et al. “Chelation-Controlled Intermolecular Hydroacylation: Direct Addition of Alkyl Aldehydes to Functionalized Alkenes.” Angewandte Chemie (International Ed. in English), vol. 43, no. 3, 2004, pp. 340–43.

Chicago Style

Willis, M, S McNally, and P Beswick. 2004. “Chelation-Controlled Intermolecular Hydroacylation: Direct Addition of Alkyl Aldehydes to Functionalized Alkenes.” Angewandte Chemie (International Ed. in English) 43 (3): 340–43.
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Publisher copy:: 10.1002/anie.200352751

Authors

+ Willis, M More by this author

Role:: Author

+ McNally, S More by this author

Role:: Author

+ Beswick, P More by this author

Role:: Author

Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 43
Issue:: 3
Pages:: 340-343
Publication date:: 2004-01-01
DOI:: 10.1002/anie.200352751
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: aldehydes

alkenes

homogeneous catalysis

hydroacylation

rhodium
Pubs id:: pubs:52460
UUID:: uuid:9bbf6f46-5745-4b89-a1df-b016ba4243cc
Local pid:: pubs:52460
Source identifiers:: 52460
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2004

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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