Journal article
Template-directed synthesis of a conjugated zinc porphyrin nanoball
- Abstract:
- We report the template-directed synthesis of a π-conjugated 14-porphyrin nanoball. This structure consists of two intersecting nanorings containing six and 10 porphyrin units. Fluorescence upconversion spectroscopy experiments demonstrate that electronic excitation delocalizes over the whole three-dimensional π system in less than 0.3 ps if the nanoball is bound to its templates or over 2 ps if the nanoball is empty.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Preview, Accepted manuscript, pdf, 7.2MB, Terms of use)
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(Preview, Accepted manuscript, pdf, 5.4MB, Terms of use)
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- Publisher copy:
- 10.1021/jacs.8b02552
Authors
- Publisher:
- American Chemical Society
- Journal:
- Journal of the American Chemical Society More from this journal
- Volume:
- 140
- Issue:
- 16
- Pages:
- 5352-5355
- Publication date:
- 2018-04-11
- Acceptance date:
- 2018-04-11
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Pmid:
-
29638125
- Language:
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English
- Pubs id:
-
pubs:843486
- UUID:
-
uuid:9b9f4aca-c8e2-4f3f-99be-c4332413930e
- Local pid:
-
pubs:843486
- Source identifiers:
-
843486
- Deposit date:
-
2018-04-21
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2018
- Notes:
- Copyright © 2018 American Chemical Society. This is the author accepted manuscript version of the article. The final version is available online from American Chemical Society at: https://doi.org/10.1021/jacs.8b02552
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