Journal article

An in situ copper plated boron-doped diamond microelectrode array for the sensitive electrochemical detection of nitrate

Abstract:: The first example of using a copper microelectrode array for use in electroanalysis is explored and exemplified with the electroanalytical quantification of nitrate. The analytical approach is based upon the in situ deposition of copper at a boron-doped diamond (BDD) microelectrode array. The immobilized copper layer is electrocatalytic for nitrate reduction and exhibits an analytically useful range from 1.2 to 124 μM with a marked selectivity for nitrate ion over nitrate, with a limit of detection of 0.76 μM. The analytical applicability was examined through standard addition determinations of nitrate in drinking and river water samples. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA.

Publication status:: Published

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Cite

Cite this record

APA Style

Ward-Jones, S., Banks, C., Simm, A., Jiang, L., & Compton, R. (2005). An in situ copper plated boron-doped diamond microelectrode array for the sensitive electrochemical detection of nitrate. ELECTROANALYSIS, 17(20), 1806–1815.

MLA Style

Ward-Jones, S., et al. “An in Situ Copper Plated Boron-Doped Diamond Microelectrode Array for the Sensitive Electrochemical Detection of Nitrate.” ELECTROANALYSIS, vol. 17, no. 20, 2005, pp. 1806–15.

Chicago Style

Ward-Jones, S, C Banks, A Simm, L Jiang, and R Compton. 2005. “An in Situ Copper Plated Boron-Doped Diamond Microelectrode Array for the Sensitive Electrochemical Detection of Nitrate.” ELECTROANALYSIS 17 (20): 1806–15.
Share
Print

Access Document

Publisher copy:: 10.1002/elan.200503316

Authors

+ Ward-Jones, S More by this author

Role:: Author

+ Banks, C More by this author

Role:: Author

+ Simm, A More by this author

Role:: Author

+ Jiang, L More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: ELECTROANALYSIS More from this journal
Volume:: 17
Issue:: 20
Pages:: 1806-1815
Publication date:: 2005-10-01
DOI:: 10.1002/elan.200503316
EISSN:: 1521-4109
ISSN:: 1040-0397

Language:: English
Keywords:: copper modification

copper microelectrode array

electrocatalysis

boron-doped diamond array

nitrate detection
Pubs id:: pubs:39695
UUID:: uuid:9b3ea29d-1059-4048-a429-ad7ee6103be6
Local pid:: pubs:39695
Source identifiers:: 39695
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP