- Abstract:
- Ph2PCl easily inserts into the Ta-H bond of Cp2TaH3 affording an ionic complex [Cp2TaH2(HPPh2)]Cl (4). This species was deprotonated to give the first phosphido-substituted tantalocene complex Cp2TaH2PPh2 (5), which was characterized by NMR spectroscopy and X-ray crystallography. Thermal decomposition of 5 as well as its reaction with HPPh2 was studied. © 1995 American Chemical Society.
- Publication status:
- Published
- Publisher copy:
- 10.1021/om00007a072
-
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- Journal:
- ORGANOMETALLICS
- Volume:
- 14
- Issue:
- 7
- Pages:
- 3588-3591
- Publication date:
- 1995-07-05
- DOI:
- EISSN:
-
1520-6041
- ISSN:
-
0276-7333
- URN:
-
uuid:987401bf-fbbc-4aa8-82b2-f04215d03875
- Source identifiers:
-
51483
- Local pid:
- pubs:51483
- Language:
- English
- Copyright date:
- 1995
Journal article
INSERTION OF CLPPH(2) INTO A TA-H BOND - SYNTHESIS AND STRUCTURE OF THE FIRST PHOSPHIDO DERIVATIVE OF TANTALOCENE
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