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INSERTION OF CLPPH(2) INTO A TA-H BOND - SYNTHESIS AND STRUCTURE OF THE FIRST PHOSPHIDO DERIVATIVE OF TANTALOCENE

Abstract:
Ph2PCl easily inserts into the Ta-H bond of Cp2TaH3 affording an ionic complex [Cp2TaH2(HPPh2)]Cl (4). This species was deprotonated to give the first phosphido-substituted tantalocene complex Cp2TaH2PPh2 (5), which was characterized by NMR spectroscopy and X-ray crystallography. Thermal decomposition of 5 as well as its reaction with HPPh2 was studied. © 1995 American Chemical Society.
Publication status:
Published

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Publisher copy:
10.1021/om00007a072

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS
Volume:
14
Issue:
7
Pages:
3588-3591
Publication date:
1995-07-01
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Source identifiers:
51483
Language:
English
Pubs id:
pubs:51483
UUID:
uuid:987401bf-fbbc-4aa8-82b2-f04215d03875
Local pid:
pubs:51483
Deposit date:
2012-12-19

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