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Carbohydrates in synthesis

Abstract:

The use of carbohydrates as starting materials for organic synthesis is illustrated by the synthesis of several polyhydroxylated piperidine, pyrrolidine, indolizine and pyrrolizidine alkaloids.

Nucleophilic displacement by azide ion at C-2 in a D-glucose derivative, with subsequent intramolecular cyclisation through nitrogen onto the C-6 or C-5 position and functional group manipulation, led to the synthesis of: 1,5-dideoxy-1,5-imino-D-mannitol; 1,2,5-trideoxy-1,5-imino-D-arabinohex...

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Peer review status:
Peer Reviewed

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Department:
University of Oxford
This thesis was digitised thanks to the generosity of Dr Leonard Polonsky More from this funder
Publication date:
1986
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Local pid:
polonsky:2:23

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