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Anion and pH dependent molecular motion by a halogen bonding [2]rotaxane

Abstract:
A bistable [2]rotaxane containing a halogen bonding benzimidazole–iodotriazole station directly conjugated to a naphthalimide station axle component is demonstrated to undergo macrocycle shuttling translocation only upon both protonation and chloride anion recognition. A naked-eye detectable colour response results from the co-conformational change of the host structure.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c9cc04752b

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
55
Issue:
67
Pages:
9975-9978
Place of publication:
England
Publication date:
2019-01-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pmid:
31367706


Language:
English
Pubs id:
1039641
Local pid:
pubs:1039641
Deposit date:
2020-02-03

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