Journal article
Measuring spin relaxation rates using satellite exchange NMR spectroscopy
- Abstract:
- An approach to the indirect measurement of nuclear spin relaxation rates of low‐magnetogyric ratio (γ) nuclei using the process of satellite exchange is described. The method does not require the observation of, or even the ability to provide radio‐frequency pulses to, the low‐γ nucleus, but requires this to be scalar coupled to an NMR observable nucleus, such as 31P or 1H, making it especially attractive for the study of diamagnetic transition metals. In situations where spin relaxation is dominated by chemical shift anisotropy (CSA), the determination of the longitudinal spin relaxation time constant (T1) of the metal becomes possible, as illustrated for 195Pt and 107/109Ag.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Preview, Accepted manuscript, pdf, 933.6KB, Terms of use)
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(Preview, Accepted manuscript, pdf, 615.9KB, Terms of use)
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- Publisher copy:
- 10.1002/anie.201801322
Authors
- Publisher:
- Wiley
- Journal:
- Angewandte Chemie International Edition More from this journal
- Volume:
- 57
- Issue:
- 25
- Pages:
- 7498-7502
- Publication date:
- 2018-03-25
- Acceptance date:
- 2018-03-15
- DOI:
- EISSN:
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1521-3773
- ISSN:
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1433-7851
- Pmid:
-
29575317
- Language:
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English
- Keywords:
- Pubs id:
-
pubs:833909
- UUID:
-
uuid:96907fde-654f-44bb-94bc-0d3eeb11fe36
- Local pid:
-
pubs:833909
- Source identifiers:
-
833909
- Deposit date:
-
2018-04-09
Terms of use
- Copyright holder:
- Wiley‐VCH Verlag GmbH and Co KGaA
- Copyright date:
- 2018
- Notes:
- © 2018 Wiley‐VCH Verlag GmbH and Co. KGaA, Weinheim. This is the accepted manuscript version of the article. The final version is available online from Wiley at: https://doi.org/10.1002/anie.201801322
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