Journal article
Diversity-oriented approach to CF3CHF-, CF3CFBr-, CF3CF2-, (CF3)2CH-, and CF3(SCF3)CH-substituted arenes from 1-(diazo-2,2,2-trifluoroethyl)arenes.
- Abstract:
-
Arenes substituted with perfluoroalkyl groups are attractive targets for drug and agrochemical development. Exploiting the carbenic character of donor/acceptor diazo compounds, a diversity-oriented synthesis of perfluoroalkylated arenes, for late stage fluorofunctionalization, is described. The reaction of 1-(diazo-2,2,2-trifluoroethyl)arenes with HF, F/Br, F2, CF3H, and CF3SH sources give direct access to a variety of perfluoroalkyl-substituted arenes presenting with incremental fluorine con...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/ol5030184
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Authors
Bibliographic Details
- Publisher:
- American Chemical Society
- Journal:
- Organic letters
- Volume:
- 16
- Issue:
- 22
- Pages:
- 6004-6007
- Publication date:
- 2014-11-01
- DOI:
- EISSN:
-
1523-7052
- ISSN:
-
1523-7060
- Source identifiers:
-
489778
Item Description
- Language:
- English
- Pubs id:
-
pubs:489778
- UUID:
-
uuid:965bac08-0574-4881-868d-65c3f3e17b5f
- Local pid:
- pubs:489778
- Deposit date:
- 2014-12-26
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- Copyright date:
- 2014
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