Journal article icon

Journal article

syn stereocontrol in the directed dihydroxylation of acyclic allylic alcohols

Abstract:
The preparation and directed dihydroxylation of a series of acyclic allylic alcohols is reported. The oxidation reaction is capable of demonstrating high levels of diastereoselection for the syn isomer. An explanation of the observed selectivities based on the degree of allylic strain is presented and a transition state model proposed.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1016/S0040-4039(99)01371-4

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Publisher:
Elsevier
Journal:
TETRAHEDRON LETTERS More from this journal
Volume:
40
Issue:
38
Pages:
6881-6885
Publication date:
1999-09-17
DOI:
ISSN:
0040-4039


Language:
English
Pubs id:
pubs:37136
UUID:
uuid:9638a30e-46fd-4652-aebe-4abca892541b
Local pid:
pubs:37136
Source identifiers:
37136
Deposit date:
2012-12-19

Terms of use



Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP