Journal article

CrCpTp: a high-spin Cr(II) sandwich complex with a large structural distortion.

Abstract:: CrCpTp was synthesized from the reaction of [CrCpCl](2) and KTp. Magnetic measurements indicate it to have a high-spin (S = 2) electronic configuration from 5 to 300 K. A single-crystal X-ray study reveals bond lengths typical for a high-spin configuration and a pronounced Jahn-Teller distortion. The nature of this distortion was probed by DFT calculations and the variation in bond lengths successfully reproduced. The metal-based HOMO is significantly antibonding with respect to a single pyrazolyl ring only.

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APA Style

Brunker, T., Green, J., & O'Hare, D. (2002). CrCpTp: a high-spin Cr(II) sandwich complex with a large structural distortion. Inorg Chem, 41(7), 1701–1703.

MLA Style

Brunker, T., et al. “CrCpTp: a High-Spin Cr(II) Sandwich Complex with a Large Structural Distortion.” Inorg Chem, vol. 41, no. 7, 2002, pp. 1701–03.

Chicago Style

Brunker, T, J Green, and D O'Hare. 2002. “CrCpTp: a High-Spin Cr(II) Sandwich Complex with a Large Structural Distortion.” Inorg Chem 41 (7): 1701–3.
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Publisher copy:: 10.1021/ic0255151

Authors

+ Brunker, T More by this author

Role:: Author

+ Green, J More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ O'Hare, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Inorg Chem More from this journal
Volume:: 41
Issue:: 7
Pages:: 1701-1703
Place of publication:: United States
Publication date:: 2002-04-08
DOI:: 10.1021/ic0255151
ISSN:: 0020-1669

Language:: English
Pubs id:: pubs:32086
UUID:: uuid:95d57dd8-b832-49cc-a0f5-76dacee9c21b
Local pid:: pubs:32086
Source identifiers:: 32086
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2002
Notes:: PubMed ID: 11925159

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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