Journal article
Trifluoromethylation of allylsilanes under copper catalysis.
- Abstract:
- Branched allylic CF 3 products are accessible by copper-catalyzed trifluoromethylation of allylsilanes with the Togni reagent I. The silyl group is critical to control the outcome of this reaction because in its absence, a product of addition between the alkene and the Togni reagent is formed preferentially. The reaction is inhibited with 2,2,6,6-tetramethyl-1- piperidinyloxy (TEMPO) and is likely to operate via multiple reaction pathways. Copyright © 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/chem.201201707
Authors
- Journal:
- Chemistry (Weinheim an der Bergstrasse, Germany) More from this journal
- Volume:
- 18
- Issue:
- 28
- Pages:
- 8583-8587
- Publication date:
- 2012-07-01
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:339836
- UUID:
-
uuid:95ae5d32-5e01-44ec-acd8-eba2a844e0da
- Local pid:
-
pubs:339836
- Source identifiers:
-
339836
- Deposit date:
-
2012-12-19
- ARK identifier:
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- Copyright date:
- 2012
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