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Crystal growth of pyrochlore rare-earth stannates

Abstract:
We report crystal growth of several rare-earth stannates RE 2 Sn 2 O 7 (RE=Pr, Tb, Ho, Dy, Yb and Lu) using the flux technique. Different combinations of flux were tried, and a Na 2 B 4 O 7 -NaF (1.2:1) mixture was found to be suitable for crystal growth. X-ray diffraction and thermal characterisation data are presented, as well as some initial measurements of magnetic and thermodynamic properties of the crystals. Little effect was observed with changing oxygen content by Sc substitution for Sn.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.jcrysgro.2016.10.069

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Physics; Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Physics; Condensed Matter Physics
Role:
Author


Publisher:
Elsevier
Journal:
Journal of Crystal Growth More from this journal
Volume:
468
Pages:
335-339
Publication date:
2016-11-14
Acceptance date:
2016-01-01
DOI:
ISSN:
0022-0248


Keywords:
Pubs id:
pubs:671030
UUID:
uuid:9505b19e-9702-47e0-b6ce-44bd5b4f5b0b
Local pid:
pubs:671030
Deposit date:
2017-10-27

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