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Extreme sensitivity of a topochemical reaction to cation substitution: SrVO2H versus SrV1-xTixO1.5H1.5

Abstract:

The anion-ordered oxide-hydride SrVO2H is an antiferromagnetic insulator due to strong correlations between vanadium d electrons. In an attempt to hole-dope SrVO2H into a metallic state, a strategy of first preparing SrV1-xTixO3 phases and then converting them to the corresponding SrV1-xTixO2H phases via reaction with CaH2 was followed. This revealed that the solid solution between SrVO3 and SrTiO3 is only stable at high temperature. In addition, reactions between SrV0.95Ti0.05O3 and CaH2 wer...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/acs.inorgchem.8b00026

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Physics
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
New College
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
Somerville College
ORCID:
0000-0002-6248-2063
More from this funder
Funding agency for:
Amano Patino, M
Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
57
Issue:
5
Pages:
2890–2898
Publication date:
2018-02-13
Acceptance date:
2018-02-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Pubs id:
pubs:825656
URN:
uri:94c487bd-a385-4d9b-be50-f6159b47bbb3
UUID:
uuid:94c487bd-a385-4d9b-be50-f6159b47bbb3
Local pid:
pubs:825656
Language:
English

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