- Abstract:
-
New ferrocene and cobaltocenium acetal and aldehyde containing compounds have been prepared. The acid catalysed condensations of both metallocene bis(aldehydes) (5, 6) with 1,3-dihydroxybenzene yielded complex products. The new metallocene cyclic monoaldehydes (7, 8), differed markedly in their reactions with 1,3-dihydroxybenzene with the ferrocene derivative 8 producing [1 + 1] and [1 + 2] bisphenol: aldehyde adducts, whereas the cobaltocenium analogue gave a cyclic diene compound (16). A si...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/0022-328X(95)05911-8
-
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- Journal:
- JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Volume:
- 511
- Issue:
- 1-2
- Pages:
- 207-215
- Publication date:
- 1996-04-05
- DOI:
- ISSN:
-
0022-328X
- URN:
-
uuid:9462a35c-62d9-4ef2-b9c4-769090439cc4
- Source identifiers:
-
45165
- Local pid:
- pubs:45165
- Language:
- English
- Keywords:
- Copyright date:
- 1996
Journal article
Acid catalysed condensation reactions of 1,3-dihydroxybenzene with new redox-active metallocene aldehydes
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