Journal article icon

Journal article

Acid catalysed condensation reactions of 1,3-dihydroxybenzene with new redox-active metallocene aldehydes

Abstract:

New ferrocene and cobaltocenium acetal and aldehyde containing compounds have been prepared. The acid catalysed condensations of both metallocene bis(aldehydes) (5, 6) with 1,3-dihydroxybenzene yielded complex products. The new metallocene cyclic monoaldehydes (7, 8), differed markedly in their reactions with 1,3-dihydroxybenzene with the ferrocene derivative 8 producing [1 + 1] and [1 + 2] bisphenol: aldehyde adducts, whereas the cobaltocenium analogue gave a cyclic diene compound (16). A si...

Expand abstract
Publication status:
Published

Actions


Access Document


Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
511
Issue:
1-2
Pages:
207-215
Publication date:
1996-04-05
DOI:
ISSN:
0022-328X
URN:
uuid:9462a35c-62d9-4ef2-b9c4-769090439cc4
Source identifiers:
45165
Local pid:
pubs:45165
Language:
English
Keywords:

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP