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Acid catalysed condensation reactions of 1,3-dihydroxybenzene with new redox-active metallocene aldehydes

Abstract:

New ferrocene and cobaltocenium acetal and aldehyde containing compounds have been prepared. The acid catalysed condensations of both metallocene bis(aldehydes) (5, 6) with 1,3-dihydroxybenzene yielded complex products. The new metallocene cyclic monoaldehydes (7, 8), differed markedly in their reactions with 1,3-dihydroxybenzene with the ferrocene derivative 8 producing [1 + 1] and [1 + 2] bisphenol: aldehyde adducts, whereas the cobaltocenium analogue gave a cyclic diene compound (16). A si...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
511
Issue:
1-2
Pages:
207-215
Publication date:
1996-04-05
DOI:
ISSN:
0022-328X
Source identifiers:
45165
Language:
English
Keywords:
Pubs id:
pubs:45165
UUID:
uuid:9462a35c-62d9-4ef2-b9c4-769090439cc4
Local pid:
pubs:45165
Deposit date:
2012-12-19

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