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Journal article

Unexpectedly superior enantioselectivity for trans-stilbene cis-dihydroxylation over anchored triosmium carbonyl species in confined Al-MCM-41 channels

Abstract:
Superior enantioselectivity in the dihydroxylation of trans-stilbene catalysed by anchored triosmium carbonyl species without using a chiral modifier is observed inside sterically congested MCM-41 channels; this effect is more pronounced through the introduction of surface Al sites into the silicate. © The Royal Society of Chemistry 2005.

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Publisher copy:
10.1039/b417787h

Authors


Journal:
Chemical Communications
Issue:
13
Pages:
1781-1783
Publication date:
2005-04-07
DOI:
ISSN:
1359-7345
URN:
uuid:94221b9f-9482-4207-b0f2-657966ae228c
Source identifiers:
180223
Local pid:
pubs:180223
Language:
English

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