- Abstract:
- Superior enantioselectivity in the dihydroxylation of trans-stilbene catalysed by anchored triosmium carbonyl species without using a chiral modifier is observed inside sterically congested MCM-41 channels; this effect is more pronounced through the introduction of surface Al sites into the silicate. © The Royal Society of Chemistry 2005.
- Publisher copy:
- 10.1039/b417787h
-
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- Journal:
- Chemical Communications
- Issue:
- 13
- Pages:
- 1781-1783
- Publication date:
- 2005-04-07
- DOI:
- ISSN:
-
1359-7345
- URN:
-
uuid:94221b9f-9482-4207-b0f2-657966ae228c
- Source identifiers:
-
180223
- Local pid:
- pubs:180223
- Language:
- English
- Copyright date:
- 2005
Journal article
Unexpectedly superior enantioselectivity for trans-stilbene cis-dihydroxylation over anchored triosmium carbonyl species in confined Al-MCM-41 channels
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