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Local coordination about La(3+) in molten LaCl3 and its mixtures with alkali chlorides.

Abstract:

The local structure around the La(3+) ions in molten LaCl(3) and its mixtures with alkali and alkaline earth chlorides has been investigated by using extended X-ray absorption fine structure (XAFS) and molecular dynamics (MD) techniques. Such mixtures, which are of current technological interest, are known to be thermodynamically nonideal, and there has been a good deal of work to understand the structural effects factors that contribute to the nonideality. New experimental methods allow obse...

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Publication status:
Published

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Publisher copy:
10.1021/jp910637p

Authors


Okamoto, Y More by this author
Shiwaku, H More by this author
Ikeda-Ohno, A More by this author
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Journal:
The journal of physical chemistry. A
Volume:
114
Issue:
13
Pages:
4664-4671
Publication date:
2010-04-05
DOI:
EISSN:
1520-5215
ISSN:
1089-5639
URN:
uuid:936b6c5e-b751-4ef3-bbca-88ae2d879793
Source identifiers:
369745
Local pid:
pubs:369745
Language:
English

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