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Synthesis and characterization of near-infrared absorbing benzannulated aza-BODIPY dyes.

Abstract:

A series of novel aza-diisoindolmethine dyes 9 with six different aryl and heteroaryl groups at the indole moiety have been synthesized by the addition of aryl Grignard compounds to phthalodinitrile and subsequent reaction with formamide. A plausible reaction mechanism, through a Leuckart–Wallach-type reduction has been confirmed by means of DFT calculations of the related transition and intermediate states. The corresponding boron difluoride complexes (10) o...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/chem.201002941

Authors


Gresser, R More by this author
Hummert, M More by this author
Hartmann, H More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
Publisher:
WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim Publisher's website
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany) Journal website
Volume:
17
Issue:
10
Pages:
2939-2947
Publication date:
2011-03-05
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:92e6ae2e-9143-48de-a369-38a58150f1bb
Source identifiers:
403014
Local pid:
pubs:403014

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