- Abstract:
-
The photoinduced, multicomponent reaction of α-diazoketones, silanols, and isocyanides affords α-silyloxy acrylamides, formally derived from α-keto amides. The presence of a secondary amido group makes classic preparative methods for silyl enol ethers unfeasible in this case, while the mild conditions required by this photochemical approach allow their synthesis in good yields; moreover, the general structure can be easily modified by varying each component of the multicomponent reaction. Fin...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Publisher copy:
- 10.1021/acs.orglett.8b00009
-
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- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Organic Letters Journal website
- Volume:
- 20
- Issue:
- 4
- Pages:
- 1098-1101
- Publication date:
- 2018-01-30
- Acceptance date:
- 2018-01-25
- DOI:
- EISSN:
-
1523-7052
- ISSN:
-
1523-7060
- Pubs id:
-
pubs:827773
- URN:
-
uri:92a916ce-4650-49b0-b57c-3a6a90e50a8f
- UUID:
-
uuid:92a916ce-4650-49b0-b57c-3a6a90e50a8f
- Local pid:
- pubs:827773
- Language:
- English
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2018
- Notes:
- Copyright © 2018 American Chemical Society.
Journal article
Photoinduced multicomponent synthesis of α-silyloxy acrylamides, an unexplored class of silyl enol ethers
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