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Partitioning behaviour of 1-hexanol into lipid membranes as studied by deuterium NMR spectroscopy.

Abstract:

Deuterium nuclear magnetic resonance (NMR) spectroscopy was used to study the partitioning behaviour of 1-hexanol specifically deuterated in the alpha-position into model lipid bilayers. In all systems studied, the observed deuterium NMR lineshapes were time-dependent. Initially, 1-hexanol-d2 gave rise to an isotropic deuterium resonance with a different chemical shift from that of aqueous 1-hexanol-d2. After equilibration over a period of days, a broader spectral component characteristic of ...

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Publication status:
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Authors


Fraser, DM More by this author
Van Gorkom, LC More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MSD, Biochemistry
Journal:
Biochimica et biophysica acta
Volume:
1069
Issue:
1
Pages:
53-60
Publication date:
1991-10-05
DOI:
ISSN:
0006-3002
URN:
uuid:9199864f-0400-4b68-adb1-e10d35946143
Source identifiers:
170085
Local pid:
pubs:170085

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