Journal article

Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory

Abstract:: Analytical theory is developed for EC and ECE processes, both homogeneous and heterogeneous, occurring at channel electrodes for the case where the electron transfer is electrochemically reversible. In particular the variation of the half-wave potential with solution flow rate and/or cell geometry is shown to provide a sensitive indication of electrode reaction mechanism type. Simple expressions are presented which allow the ready mechanistic interpretation of experimental data and the deduction of corresponding rate constants.

Publication status:: Published

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APA Style

Morland, P., & Compton, R. (1999). Heterogeneous and homogeneous EC and ECE processes at channel electrodes: Analytical wave shape theory. JOURNAL OF PHYSICAL CHEMISTRY B, 103(42), 8951–8959.

MLA Style

Morland, P., and R. Compton. “Heterogeneous and Homogeneous EC and ECE Processes at Channel Electrodes: Analytical Wave Shape Theory.” JOURNAL OF PHYSICAL CHEMISTRY B, vol. 103, no. 42, 1999, pp. 8951–59.

Chicago Style

Morland, P, and R Compton. 1999. “Heterogeneous and Homogeneous EC and ECE Processes at Channel Electrodes: Analytical Wave Shape Theory.” JOURNAL OF PHYSICAL CHEMISTRY B 103 (42): 8951–59.
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Publisher copy:: 10.1021/jp991922v

Authors

+ Morland, P More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: JOURNAL OF PHYSICAL CHEMISTRY B More from this journal
Volume:: 103
Issue:: 42
Pages:: 8951-8959
Publication date:: 1999-10-21
DOI:: 10.1021/jp991922v
EISSN:: 1520-5207
ISSN:: 1089-5647

Language:: English
Pubs id:: pubs:37216
UUID:: uuid:8f988a2f-2e4f-4039-becc-87e97c456e3d
Local pid:: pubs:37216
Source identifiers:: 37216
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1999

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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