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Solution-based Group 14 Zintl anions: new frontiers and discoveries

Abstract:

Group 14 Zintl anions [Ex]q (E = Si–Pb, x = 4, 5, 9, 10) are synthetically accessible, and their diverse chemical reactivity makes them valuable synthons in the construction of larger nanoclusters with remarkable structures, intriguing patterns of chemical bonding, and tunable physical and chemical properties. A plethora of novel cluster anions have now been isolated from the reactions of polyanionic [Ex<...>

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.accounts.0c00876

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
New College
Role:
Author
ORCID:
0000-0002-8991-1921
More by this author
Role:
Author
ORCID:
0000-0003-2894-6327


Publisher:
American Chemical Society
Journal:
Accounts of Chemical Research More from this journal
Volume:
54
Issue:
6
Pages:
1506-1516
Publication date:
2021-03-08
Acceptance date:
2021-03-08
DOI:
EISSN:
1520-4898
ISSN:
0001-4842
Pmid:
33677965


Language:
English
Keywords:
Pubs id:
1167751
Local pid:
pubs:1167751
Deposit date:
2023-01-15

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