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Journal article

Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere

Abstract:
Visible-to-near-infrared observations indicate that the cloud top of the main cloud deck on Uranus lies at a pressure level of between 1.2 bar and 3 bar. However, its composition has never been unambiguously identified, although it is widely assumed to be composed primarily of either ammonia or hydrogen sulfide (H2S) ice. Here, we present evidence of a clear detection of gaseous H2S above this cloud deck in the wavelength region 1.57–1.59 μm with a mole fraction of 0.4–0.8 ppm at the cloud top. Its detection constrains the deep bulk sulfur/nitrogen abundance to exceed unity (>4.4–5.0 times the solar value) in Uranus’s bulk atmosphere, and places a lower limit on the mole fraction of H2S below the observed cloud of (1.0−2.5)×10−5. The detection of gaseous H2S at these pressure levels adds to the weight of evidence that the principal constituent of 1.2–3-bar cloud is likely to be H2S ice.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1038/s41550-018-0432-1

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Atmos Ocean & Planet Physics
Oxford college:
St Anne's College
Role:
Author
ORCID:
0000-0002-6772-384X
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Physics; Atmos Ocean & Planet Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Physics; Atmos Ocean & Planet Physics
Role:
Author


Publisher:
Nature Publishing Group
Journal:
Nature Astronomy More from this journal
Volume:
2
Issue:
2018
Pages:
420-427
Publication date:
2018-04-23
Acceptance date:
2018-02-27
DOI:
ISSN:
2397-3366


Keywords:
Pubs id:
pubs:844223
UUID:
uuid:8ef4459a-29ec-4420-87af-e149c4f35c73
Local pid:
pubs:844223
Source identifiers:
844223
Deposit date:
2018-04-25

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