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Lanthanide borohydride complexes supported by diaminobis(phenoxide) ligands for the polymerization of epsilon-caprolactone and L- and rac-lactide.

Abstract:

Reaction of Na2O2NN' [H2O2NN' = (2-C5H4N)CH2N[2-HO-3,5-C6H2(t)Bu2]2] with M(BH4)3(THF)3 afforded the dimeric, rare-earth borohydride compounds [M(O2NN')(mu-BH4)(THF)n]2 [M = Y(III), n = 0.5 (1-Y); M = NdIII, n = 1 (1-Nd); M = SmIII, n = 0 (1-Sm)]. For comparison the chloride analogues [M(O2NN')(mu-Cl)(THF)n]2 (2-M; M = La(III) or Sm(III), n = 0; M = Nd(III), n = 1) and the corresponding pyridine adducts [M(O2NN')(mu-X)(py)]2 [X = BH4 (3-M) or Cl (4-M); M = La(III), Nd(III), or Sm(III)] were p...

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Publication status:
Published

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Publisher copy:
10.1021/ic051316g

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More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry More from this journal
Volume:
44
Issue:
24
Pages:
9046-9055
Publication date:
2005-11-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Language:
English
Keywords:
Pubs id:
pubs:51048
UUID:
uuid:8d767d11-ca71-4932-bf6a-d339646a4c17
Local pid:
pubs:51048
Source identifiers:
51048
Deposit date:
2012-12-19

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