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An experimental comparison of the Marcus-Hush and Butler-Volmer descriptions of electrode kinetics applied to cyclic voltammetry. The one electron reductions of europium (III) and 2-methyl-2-nitropropane studied at a mercury microhemisphere electrode

Abstract:: We present a comparative experimental evaluation of the Butler-Volmer and Marcus-Hush models using cyclic voltammetry at a microelectrode. Numerical simulations are used to fit experimental voltammetry of the one electron reductions of europium (III) and 2-methyl-2-nitropropane, in water and acetonitrile, respectively, at a mercury microhemisphere electrode. For Eu (III) very accurate fits to experiment were obtained over a wide range of scan rates using Butler-Volmer kinetics, whereas the Ma...
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APA Style

Henstridge, M., Wang, Y., Limon-Petersen, J., Laborda, E., & Compton, R. (2011). An experimental comparison of the Marcus-Hush and Butler-Volmer descriptions of electrode kinetics applied to cyclic voltammetry. The one electron reductions of europium (III) and 2-methyl-2-nitropropane studied at a mercury microhemisphere electrode. CHEMICAL PHYSICS LETTERS, 517(1-3), 29–35.

MLA Style

Henstridge, M., et al. “An Experimental Comparison of the Marcus-Hush and Butler-Volmer Descriptions of Electrode Kinetics Applied to Cyclic Voltammetry. The One Electron Reductions of Europium (III) and 2-Methyl-2-Nitropropane Studied at a Mercury Microhemisphere Electrode.” CHEMICAL PHYSICS LETTERS, vol. 517, no. 1-3, 2011, pp. 29–35.

Chicago Style

Henstridge, M, Y Wang, J Limon-Petersen, E Laborda, and R Compton. 2011. “An Experimental Comparison of the Marcus-Hush and Butler-Volmer Descriptions of Electrode Kinetics Applied to Cyclic Voltammetry. The One Electron Reductions of Europium (III) and 2-Methyl-2-Nitropropane Studied at a Mercury Microhemisphere Electrode.” CHEMICAL PHYSICS LETTERS 517 (1-3): 29–35.
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Publisher copy:: 10.1016/j.cplett.2011.10.004

Authors

+ Henstridge, M More by this author

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+ Wang, Y More by this author

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+ Limon-Petersen, J More by this author

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+ Laborda, E More by this author

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+ Compton, R More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Physical & Theoretical Chem

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Author

Bibliographic Details

Journal:: CHEMICAL PHYSICS LETTERS
Volume:: 517
Issue:: 1-3
Pages:: 29-35
Publication date:: 2011-11-28
DOI:: 10.1016/j.cplett.2011.10.004
ISSN:: 0009-2614

Item Description

Language:: English
Pubs id:: pubs:221667
UUID:: uuid:8d054d23-d897-4f6e-ac3f-ad21539a7746
Local pid:: pubs:221667
Source identifiers:: 221667
Deposit date:: 2012-12-19

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Copyright date:: 2011

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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