Journal article

Unusual inverse temperature dependence on reaction rate in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes.

Abstract:: Observations of an intriguing inverse temperature dependence on reaction rate and a profound induction period in the Soai autocatalytic reaction are reported along with detailed kinetic and NMR investigations of the product alkoxide at low temperatures, leading to the suggestion that the active catalyst is derived in situ from the tetrameric ground state.

Publication status:: Published

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APA Style

Quaranta, M., Gehring, T., Odell, B., Brown, J., & Blackmond, D. (2010). Unusual inverse temperature dependence on reaction rate in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes. Journal of the American Chemical Society, 132(43), 15104–15107.

MLA Style

Quaranta, M., et al. “Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes.” Journal of the American Chemical Society, vol. 132, no. 43, 2010, pp. 15104–07.

Chicago Style

Quaranta, M, T Gehring, B Odell, J Brown, and D Blackmond. 2010. “Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes.” Journal of the American Chemical Society 132 (43): 15104–7.
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Publisher copy:: 10.1021/ja103204w

Authors

+ Quaranta, M More by this author

Role:: Author

+ Gehring, T More by this author

Role:: Author

+ Odell, B More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Brown, J More by this author

Role:: Author

+ Blackmond, D More by this author

Role:: Author

Journal:: Journal of the American Chemical Society More from this journal
Volume:: 132
Issue:: 43
Pages:: 15104-15107
Publication date:: 2010-11-01
DOI:: 10.1021/ja103204w
EISSN:: 1520-5126
ISSN:: 0002-7863

Language:: English
Keywords:: Kinetics

Magnetic Resonance Spectroscopy

Catalysis

Pyrimidines

Aldehydes

Alkylation

Temperature
Pubs id:: pubs:90298
UUID:: uuid:8c95dd84-1e55-4beb-bc3f-0ca047ddfae9
Local pid:: pubs:90298
Source identifiers:: 90298
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2010

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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