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Journal article

Unusual inverse temperature dependence on reaction rate in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes.

Abstract:
Observations of an intriguing inverse temperature dependence on reaction rate and a profound induction period in the Soai autocatalytic reaction are reported along with detailed kinetic and NMR investigations of the product alkoxide at low temperatures, leading to the suggestion that the active catalyst is derived in situ from the tetrameric ground state.
Publication status:
Published

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Publisher copy:
10.1021/ja103204w

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Journal of the American Chemical Society More from this journal
Volume:
132
Issue:
43
Pages:
15104-15107
Publication date:
2010-11-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Keywords:
Pubs id:
pubs:90298
UUID:
uuid:8c95dd84-1e55-4beb-bc3f-0ca047ddfae9
Local pid:
pubs:90298
Source identifiers:
90298
Deposit date:
2012-12-19

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