Novel solid networks containing Sn-H as a greener replacement for soluble alkyl Sn-H reagents in radical assisted organic synthesis

Journal article

DiGrignard reagents of the form XMg(CH2)nMgX, where X = Br or I and n = 6, 8, 10 or 12, were allowed to react with PhSnCl 3 to produce highly cross-linked Ph-Sn polymeric networks. The Sn-H moiety was incorporated into these insoluble network polymers by treatment with Br2 and NaBH4. Excellent accessibility of the Sn-H was displayed by these solvent penetrable but insoluble networks, giving them higher Sn-H loadings than all previously reported supported reagents. These reagents were totally regenerable in NaBH4 for radical assisted organic synthesis and no detectable leaching of the Sn into solution was observed during these reactions.

Authors: Jenkins, P; Tsang, S

• Journal: Green Chemistry
• Volume: 6
• Issue: 2
• Pages: 69-71
• Publication date: 2004-02-01
• ISSN: 1463-9262
• Language: English