Journal article
Novel solid networks containing Sn-H as a greener replacement for soluble alkyl Sn-H reagents in radical assisted organic synthesis
- Abstract:
-
DiGrignard reagents of the form XMg(CH2)nMgX, where X = Br or I and n = 6, 8, 10 or 12, were allowed to react with PhSnCl 3 to produce highly cross-linked Ph-Sn polymeric networks. The Sn-H moiety was incorporated into these insoluble network polymers by treatment with Br2 and NaBH4. Excellent accessibility of the Sn-H was displayed by these solvent penetrable but insoluble networks, giving them higher Sn-H loadings than all previously reported supported reagents. These reagents were totally ...
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Bibliographic Details
- Journal:
- Green Chemistry
- Volume:
- 6
- Issue:
- 2
- Pages:
- 69-71
- Publication date:
- 2004-02-01
- ISSN:
-
1463-9262
Item Description
- Language:
- English
- Pubs id:
-
pubs:180224
- UUID:
-
uuid:8c8be2bd-0bc5-4ae0-9982-54a7f2f94224
- Local pid:
- pubs:180224
- Source identifiers:
-
180224
- Deposit date:
- 2013-02-20
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- Copyright date:
- 2004
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