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Kinetically controlled synthesis of two-dimensional Zr/Hf metal–organic framework nanosheets via a modulated hydrothermal approach

Abstract:

The kinetically controlled synthesis of two-dimensional (2D) metal-organic framework (MOF) nanosheets in the absence of surfactants is rewarding but challenging. We herein describe such a surfactant-free bottom-up synthesis of 2D stable Zr/Hf MOF nanosheets named NUS-8 composed of Zr 6 O 4 (OH) 4 or Hf 6 O 4 (OH) 4 clusters and 1,3,5-benzenetribenzoate (BTB 3- ) via a modulated hydrothermal approach, which allows fast precipitation and stabilization of intermediate 2D metal-organic nanoshe...

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Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1039/C7TA00413C

Authors


Singapore Ministry of Education More from this funder
National University of Singapore More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Journal of Materials Chemistry A Journal website
Volume:
5
Issue:
19
Pages:
8954-8963
Publication date:
2017-04-01
Acceptance date:
2017-03-21
DOI:
EISSN:
2050-7496
ISSN:
2050-7488
Keywords:
Pubs id:
pubs:708747
UUID:
uuid:8a5176ea-5c37-4ea3-8f5c-6526583a278b
Local pid:
pubs:708747
Source identifiers:
708747
Deposit date:
2017-08-03

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