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Thermal and light induced polymorphism in iron(II) spin crossover compounds.

Abstract:
The spin crossover complexes [Fe[H(2)B(pz)(2)](2)L]([H(2)B(pz)(2)](-)= dihydrobis(pyrazolyl)borate, L = 2,2[prime or minute]-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for are different from that of the thermally induced high spin state and from those of.
Publication status:
Published

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Publisher copy:
10.1039/b403179b

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Carmen Munoz, M More by this author
Journal:
Chemical communications (Cambridge, England)
Volume:
10
Issue:
12
Pages:
1390-1391
Publication date:
2004-06-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:89568b9b-c6a7-435e-abd2-b651326749d5
Source identifiers:
117123
Local pid:
pubs:117123
Language:
English

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