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The cyclic voltammetric response of electrochemically heterogeneous surfaces

Abstract:

The cyclic voltammetric response of an electrode composed of two different electrode materials is modelled using finite difference simulations. The system can be thought of as an array of microelectrodes of one material dispersed over a different electrode material. First, a detailed study into the diffusional effects which arise when the distance between the individual microelectrodes is varied, leads to a simple method with which to obtain qualitative data regarding the size of the differen...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
574
Issue:
1
Pages:
123-152
Publication date:
2004-12-15
DOI:
ISSN:
0022-0728
URN:
uuid:88a50d8e-96c1-4f31-9837-265593bcdc53
Source identifiers:
39314
Local pid:
pubs:39314

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