Journal article
Cyclic voltammetry with non-triangular waveforms: Electrochemically irreversible and quasi-reversible systems
- Abstract:
- The voltammetry of electrochemically-irreversible and quasi-reversible reactions are investigated theoretically at a macroelectrode for the case of an applied cosine square-based potential waveform. The results reveal distinct features in the voltammograms which can be exploited to determine the electrochemical transfer coefficient, α and the standard electrochemical rate constant, k 0 , of a reaction with high sensitivity.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Accepted manuscript, pdf, 849.3KB, Terms of use)
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- Publisher copy:
- 10.1016/j.jelechem.2017.12.053
Authors
+ European Research Council
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- Grant:
- European Union's Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement no. [320403
- Publisher:
- Elsevier
- Journal:
- Journal of Electroanalytical Chemistry More from this journal
- Volume:
- 810
- Pages:
- 135-144
- Publication date:
- 2017-12-29
- Acceptance date:
- 2017-12-20
- DOI:
- ISSN:
-
1572-6657
- Keywords:
- Pubs id:
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pubs:821033
- UUID:
-
uuid:8821ce42-9a84-4280-95f6-98226a593a49
- Local pid:
-
pubs:821033
- Source identifiers:
-
821033
- Deposit date:
-
2018-01-24
- ARK identifier:
Terms of use
- Copyright holder:
- Elsevier BV
- Copyright date:
- 2017
- Notes:
- Copyright © 2017 Elsevier B.V. This is the accepted manuscript version of the article. The final version is available online from Elsevier at: https://doi.org/10.1016/j.jelechem.2017.12.053
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