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Cyclic voltammetry with non-triangular waveforms: Electrochemically irreversible and quasi-reversible systems

Abstract:
The voltammetry of electrochemically-irreversible and quasi-reversible reactions are investigated theoretically at a macroelectrode for the case of an applied cosine square-based potential waveform. The results reveal distinct features in the voltammograms which can be exploited to determine the electrochemical transfer coefficient, α and the standard electrochemical rate constant, k 0 , of a reaction with high sensitivity.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1016/j.jelechem.2017.12.053

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Oxford college:
Keble College
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Physical & Theoretical Chem
Oxford college:
St Johns College
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Grant:
European Union's Seventh Framework Programme (FP/2007-2013)/ERC Grant Agreement no. [320403]
Publisher:
Elsevier Publisher's website
Journal:
Journal of Electroanalytical Chemistry Journal website
Volume:
810
Pages:
135-144
Publication date:
2017-12-29
Acceptance date:
2017-12-20
DOI:
ISSN:
1572-6657
Pubs id:
pubs:821033
URN:
uri:8821ce42-9a84-4280-95f6-98226a593a49
UUID:
uuid:8821ce42-9a84-4280-95f6-98226a593a49
Local pid:
pubs:821033

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