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Journal article

MAGNETISM AND SUPERCONDUCTIVITY IN THE SPINEL SYSTEM LI-1-XMN-2+TI2O4, LI-1-XMG-2+TI2O4

Abstract:

X-ray powder diffraction measurements show that the M2+ cations substitute almost completely at the tetrahedral sites in the Li1-xMxTi2O4 spinel systems (M = Mn2+, 0 < x < 1; M = Mg2+, 0 < x < 0.2). The magnetic susceptibility of the Li1-xMxTi2O4 system is dominated by high-spin Mn2+ moments for x < 0.5 and shows ferrimagnetic ordering at low temperatures (15-55 K) for samples with higher x compositions. The occurrence of spontaneous magnetism in the Li0.4Mn0.6Ti2O4 sample is i...

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Publication status:
Published

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Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
75
Issue:
2
Pages:
332-346
Publication date:
1988-08-01
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
Language:
English
Pubs id:
pubs:46481
UUID:
uuid:8782bb56-51e7-48f1-81b7-5d5c60833f8a
Local pid:
pubs:46481
Source identifiers:
46481
Deposit date:
2012-12-19

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