A C-linked glycomimetic in the gas phase and in solution: synthesis and conformation of the disaccharide Manalpha(1,6)-C-ManalphaOPh.

Drouin, L; Stanca-Kaposta, EC; Saundh, P; Fairbanks, AJ; Kemper, S; Claridge, TD; Simons, JP

Abstract:

The effect of carbon is subtle but sweet: The flexible C-linkage in the newly synthesised C-glycosyl mimetic, Manalpha(1,6)-C-ManalphaOPh allows OH--pi bonding, both in the gas phase and in aqueous solution. This interaction is absent in the O-linked disaccharide (see figure).The intrinsic conformational preference of a newly synthesised glycomimetic, the C-linked disaccharide Manalpha(1,6)-C-ManalphaOPh (1), has been determined in the gas phase at about 10 K by infrared ion dip spectroscopy ...

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APA Style

Drouin, L., Stanca-Kaposta, E. C., Saundh, P., Fairbanks, A. J., Kemper, S., Claridge, T. D., & Simons, J. P. (2009). A C-linked glycomimetic in the gas phase and in solution: synthesis and conformation of the disaccharide Manalpha(1,6)-C-ManalphaOPh. Chemistry (Weinheim an Der Bergstrasse, Germany), 15(16), 4057–4069.

MLA Style

Drouin, L., et al. “A C-Linked Glycomimetic in the Gas Phase and in Solution: Synthesis and Conformation of the Disaccharide Manalpha(1,6)-C-ManalphaOPh.” Chemistry (Weinheim an Der Bergstrasse, Germany), vol. 15, no. 16, Chemistry (Weinheim an der Bergstrasse, Germany), 2009, pp. 4057–69.

Chicago Style

Drouin, L, EC Stanca-Kaposta, P Saundh, AJ Fairbanks, S Kemper, TD Claridge, and JP Simons. 2009. “A C-Linked Glycomimetic in the Gas Phase and in Solution: Synthesis and Conformation of the Disaccharide Manalpha(1,6)-C-ManalphaOPh.” Chemistry (Weinheim an Der Bergstrasse, Germany) 15 (16): 4057–69.
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