Journal article
A C-linked glycomimetic in the gas phase and in solution: synthesis and conformation of the disaccharide Manalpha(1,6)-C-ManalphaOPh.
- Abstract:
-
The effect of carbon is subtle but sweet: The flexible C-linkage in the newly synthesised C-glycosyl mimetic, Manalpha(1,6)-C-ManalphaOPh allows OH--pi bonding, both in the gas phase and in aqueous solution. This interaction is absent in the O-linked disaccharide (see figure).The intrinsic conformational preference of a newly synthesised glycomimetic, the C-linked disaccharide Manalpha(1,6)-C-ManalphaOPh (1), has been determined in the gas phase at about 10 K by infrared ion dip spectroscopy ...
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- Publication status:
- Published
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- Publisher copy:
- 10.1002/chem.200802179
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Bibliographic Details
- Journal:
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Volume:
- 15
- Issue:
- 16
- Pages:
- 4057-4069
- Publication date:
- 2009-01-01
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- URN:
-
uuid:86d9f934-aa13-4568-9b66-360de38811ff
- Source identifiers:
-
117889
- Local pid:
- pubs:117889
Item Description
- Language:
- English
- Keywords:
Terms of use
- Copyright date:
- 2009
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