Journal article icon

Journal article

The influence of pesticides on the corrosion of a Roman bowl excavated in Kent, UK

Abstract:
We analysed corrosion from a copper bowl dating from the Roman period (43-410 AD) found in a farm in Kent, UK. Despite its relatively good condition, the interior and exterior surface of the object had areas of deterioration containing green and brown-coloured corrosion which were sampled for characterization by a multi-analytical protocol. Basic copper chlorides atacamite and paratacamite were identified in the context of mineral phases along with chlorobenzenes in the green corrosion. Chlorobenzenes are common soil contaminants in rural areas from the use of pesticides, many of which were banned more than 50 years ago. Here we show that their presence is associated with accelerated corrosion, and this provides a threat to the preservation of archaeological metal objects in the ground.
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1038/s41598-022-17902-9

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Oxford college:
Linacre College
Role:
Author
ORCID:
0000-0003-1884-3121
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Oxford college:
Merton College
Role:
Author
ORCID:
0000-0003-4733-1205
More by this author
Institution:
University of Oxford
Division:
SSD
Department:
School of Archaeology
Role:
Author


Publisher:
Springer Nature
Journal:
Scientific Reports More from this journal
Volume:
12
Issue:
1
Article number:
14521
Place of publication:
England
Publication date:
2022-10-06
Acceptance date:
2022-08-02
DOI:
EISSN:
2045-2322
Pmid:
36202853


Language:
English
Keywords:
Pubs id:
1281681
Local pid:
pubs:1281681
Deposit date:
2024-08-15

Terms of use



Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP