Journal article
Arylsulfonyl fluoride boronic acids: preparation and coupling reactivity
- Abstract:
- We report the efficient and practical syntheses of ortho-, meta, and para-sulfonyl fluoride substituted benzene boronic acids. The syntheses of the para- and meta-isomers commence with the appropriate bromo-substituted benzenesulfonyl chlorides, and the ortho-isomer is prepared from benzenesulfonyl fluoride. The boronic acids undergo efficient Sukuki-Miyaura coupling reactions with a range of aryl halides. We also report an efficient Rh(I)-catalyzed conjugate addition reaction using the para-substituted boronic acid.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Preview, Accepted manuscript, pdf, 685.5KB, Terms of use)
-
- Publisher copy:
- 10.1016/j.tet.2019.130782
Authors
- Publisher:
- Elsevier
- Journal:
- Tetrahedron More from this journal
- Volume:
- 76
- Issue:
- 1
- Article number:
- 130782
- Publication date:
- 2019-11-18
- Acceptance date:
- 2019-11-08
- DOI:
- ISSN:
-
0040-4020
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:1070542
- UUID:
-
uuid:84e825ab-8db9-4169-b8b7-811ba0396c6b
- Local pid:
-
pubs:1070542
- Source identifiers:
-
1070542
- Deposit date:
-
2019-11-08
Terms of use
- Copyright holder:
- Elsevier Ltd
- Copyright date:
- 2019
- Rights statement:
- © 2019 Elsevier Ltd. All rights reserved.
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from Elsevier at: https://doi.org/10.1016/j.tet.2019.130782
If you are the owner of this record, you can report an update to it here: Report update to this record