Journal article

CuTi LDH derived NH 3 -SCR catalysts with highly dispersed CuO active phase and improved SO 2 resistance

Abstract:: Dispersed CuyTi1Ox catalysts derived from Cu-Ti-CO3 layered double hydroxides (LDHs) were successfully prepared. Due to the better dispersion of active CuO phase, the optimal catalyst Cu1Ti1Ox reached a high NOx conversion of 88.9% at 200 °C, which is significantly higher than that of the control catalyst 10 wt% CuO/TiO2 (29.5%). Cu1Ti1Ox catalyst also showed improved SO2 resistance, with a very stable NOx conversion of 76.4% at 200 °C after 8 h running with 50 ppm SO2, much higher than that of 10 wt% CuO/TiO2 (3.3%). The reaction mechanism was discussed with NH3-TPD and H2-TPR analyses, which indicated that Cu1Ti1Ox has more surface acidic sites and higher redox property than 10 wt% CuO/TiO2. In all, CuyTi1Ox prepared from Cu-Ti LDH precursor can work as highly efficient and SO2 resistant low-temperature NH3-SCR catalyst for NOx removal.

Publication status:: Published

Peer review status:: Peer reviewed

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Share
Cite

Cite this record

APA Style

Nie, Y., Yan, Q., Chen, S., O'Hare, D., & Wang, Q. (2017). CuTi LDH derived NH 3 -SCR catalysts with highly dispersed CuO active phase and improved SO 2 resistance. Catalysis Communications, 97, 47–50.

MLA Style

Nie, Y, et al. “CuTi LDH Derived NH 3 -SCR Catalysts with Highly Dispersed CuO Active Phase and Improved SO 2 Resistance.” Catalysis Communications, vol. 97, 2017, pp. 47–50.

Chicago Style

Nie, Y, Q Yan, S Chen, D O'Hare, and Q Wang. 2017. “CuTi LDH Derived NH 3 -SCR Catalysts with Highly Dispersed CuO Active Phase and Improved SO 2 Resistance.” Catalysis Communications 97: 47–50.
Print

Access Document

Files:: Revised manuscript.pdf

(Preview, Accepted manuscript, pdf, 2.4MB, Terms of use)

Publisher copy:: 10.1016/j.catcom.2017.04.014

Authors

+ Nie, Y More by this author

Role:: Author

+ Yan, Q More by this author

Role:: Author

+ Chen, S More by this author

Role:: Author

+ O'Hare, D More by this author

Institution:: University of Oxford
Oxford college:: Balliol College
Role:: Author

+ Wang, Q More by this author

Role:: Author

+ Beijing Excellent Young Scholar More from this funder

Grant:: 2015000026833ZK11

+ National Natural Science Foundation of China More from this funder

Grant:: 51622801,51572029,; 51308045

+ Fundamental Research Funds for the Central Universities More from this funder

Grant:: 2016ZCQ03

Publisher:: Elsevier
Journal:: Catalysis Communications More from this journal
Volume:: 97
Pages:: 47-50
Publication date:: 2017-04-07
Acceptance date:: 2017-04-06
DOI:: 10.1016/j.catcom.2017.04.014
EISSN:: 1566-7367

Keywords:: low temperature NH3-SCR

SO2 resistance

high activity

Cu-Ti layered double hydroxides
Pubs id:: pubs:691384
UUID:: uuid:84212c94-10d2-4c4d-a9d6-7a2b0ab92a6b
Local pid:: pubs:691384
Source identifiers:: 691384
Deposit date:: 2017-08-23
ARK identifier:: ark:/29072/ora_84212c9410d24c4da9d67a2b0ab92a6b

Terms of use

Copyright holder:: Elsevier
Copyright date:: 2017
Notes:: Copyright © 2017 Elsevier B.V. This is the accepted manuscript version of the article. The final version is available online from Elsevier at: https://doi.org/10.1016/j.catcom.2017.04.014

Licence:: CC Attribution-NonCommercial-NoDerivatives (CC BY-NC-ND)

Views and Downloads

Views and downloads will return soon

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP