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Voltammetric waveshapes measured in flowing systems: Mass transport-limited tafel analysis of some nonsimple systems

Abstract:
Analytical theory is presented which allows rigorous mass transport-corrected Tafel analysis for the reversible electrode processes (1) 2B ⇄ A2 + 2e− and (2) B2 ⇄ 2A + 2e− occurring at electrodes in flowing systems. Predictions are compared with the conclusions of numerical finite-difference modelling for both wall-jet and channel flow cell geometries. Exceillent agreement is found.
Publication status:
Published

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Publisher copy:
10.1002/elan.1140050715

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Institution:
University of Oxford
Role:
Author
More by this author
Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author


Journal:
Electroanalysis More from this journal
Volume:
5
Issue:
7
Pages:
615-617
Publication date:
1993-08-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397


Keywords:
Pubs id:
pubs:44306
UUID:
uuid:83bc0c79-cc11-451d-b696-4fae98ec307f
Local pid:
pubs:44306
Source identifiers:
44306
Deposit date:
2012-12-19

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