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Amperometric environmental phosphate sensor

Abstract:
We report a novel amperometric sensor for aqueous phosphate ions in freshwater systems based on the reductive square wave voltammetry of molybdate (VI) anions immobilized within a chitosan matrix deposited on a glassy carbon electrode. A sensitivity of 4.4±0.1 μA/μM was realized together with a LOD of 0.15 μM. The sensor was insensitive to chloride and nitrate ions below threshold concentration of 1.0 mM respectively. Analytical measurements were successfully made in authentic samples of tap and pond water.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acssensors.1c01035

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
ORCID:
0000-0001-5869-9975


Publisher:
American Chemical Society
Journal:
ACS Sensors More from this journal
Volume:
6
Issue:
9
Pages:
3284–3294
Publication date:
2021-08-20
Acceptance date:
2021-08-11
DOI:
EISSN:
2379-3694


Language:
English
Keywords:
Pubs id:
1191482
Local pid:
pubs:1191482
Deposit date:
2021-08-18
ARK identifier:

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