- Abstract:
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The use of solid/gas and single-crystal to single-crystal synthetic routes is reported for the synthesis and characterization of a number of σ-alkane complexes: [Rh(R2P(CH2)nPR2)(η(2),η(2)-C7H12)][BAr(F)4]; R = Cy, n = 2; R = (i)Pr, n = 2,3; Ar = 3,5-C6H3(CF3)2. These norbornane adducts are formed by simple hydrogenation of the corresponding norbornadiene precursor in the solid state. For R = Cy (n = 2), the resulting complex is remarkably stable (months at 298 K), allowing for full character...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 3.2MB)
-
- Publisher copy:
- 10.1021/ja510437p
-
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- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 137
- Issue:
- 2
- Pages:
- 820–833
- Publication date:
- 2014-12-15
- DOI:
- ISSN:
-
1520-5126 and 0002-7863
- Pubs id:
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pubs:505138
- URN:
-
uri:82359fab-635d-459b-ab36-ea9a99c9a6f9
- UUID:
-
uuid:82359fab-635d-459b-ab36-ea9a99c9a6f9
- Local pid:
- pubs:505138
- Paper number:
- 2
- Language:
- English
- Keywords:
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2014
- Notes:
- This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Journal article
Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine)
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Engineering and Physical Sciences Research Council
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