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Solid-state synthesis and characterization of σ-alkane complexes, [Rh(L2)(η(2),η(2)-C7H12)][BAr(F)4] (L2 = bidentate chelating phosphine)

Abstract:

The use of solid/gas and single-crystal to single-crystal synthetic routes is reported for the synthesis and characterization of a number of σ-alkane complexes: [Rh(R2P(CH2)nPR2)(η(2),η(2)-C7H12)][BAr(F)4]; R = Cy, n = 2; R = (i)Pr, n = 2,3; Ar = 3,5-C6H3(CF3)2. These norbornane adducts are formed by simple hydrogenation of the corresponding norbornadiene precursor in the solid state. For R = Cy (n = 2), the resulting complex is remarkably stable (months at 298 K), allowing for full character...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/ja510437p

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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Author
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Department:
Magdalen College
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Engineering and Physical Sciences Research Council More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
137
Issue:
2
Pages:
820–833
Publication date:
2014-12-15
DOI:
ISSN:
1520-5126 and 0002-7863
Pubs id:
pubs:505138
URN:
uri:82359fab-635d-459b-ab36-ea9a99c9a6f9
UUID:
uuid:82359fab-635d-459b-ab36-ea9a99c9a6f9
Local pid:
pubs:505138
Paper number:
2
Language:
English
Keywords:

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