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Actinide tetra-N-heterocyclic carbene ‘sandwiches’

Abstract:

Organometallic actinide chemistry is still a field that is in its infancy. The birth of the area can be traced back to the isolation of the first "actinocene", Uranocene, in 1968. Given the complexity of the 5f orbital manifold, descriptions of actinide ligand bonding are to this day still being investigated at a fundamental level, with competing schools of thought asserting their perspective on bonding and electronic structure. This task is not made easier through comparisons with the lantha...

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Publication status:
Published
Peer review status:
Peer reviewed

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Role:
Author
ORCID:
0000-0002-3857-5008
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Institution:
University of Oxford
Role:
Author
ORCID:
0000-0002-8045-2060
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Role:
Author
ORCID:
0000-0002-7430-9452
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Role:
Author
ORCID:
0000-0003-1950-6960


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Funder identifier:
10.13039/501100000780
Grant:
740311
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Funder identifier:
10.13039/100000015
Grant:
DE-AC02-05CH11231
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Funder identifier:
10.13039/501100000266
Grant:
EP/L016419/1
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Funder identifier:
10.13039/100006151
Grant:
DE-AC02-05CH11231
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Funder identifier:
10.13039/501100000848


Publisher:
Royal Society of Chemistry
Journal:
Chemical Science More from this journal
Volume:
12
Issue:
22
Pages:
7882-7887
Publication date:
2021-06-09
DOI:
EISSN:
2041-6539
ISSN:
2041-6520


Language:
English
Keywords:
Pubs id:
1246352
Local pid:
pubs:1246352
Source identifiers:
W3163913805
Deposit date:
2026-04-10
ARK identifier:
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