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Group 5 ansa-metallocenes: Structural and dynamic properties of tetrahydroborate complexes

Abstract:

The new compounds [Nb{(eta-C5H4)X(eta-C5H4)}Cl-2] (X = CEt2 1a, C(C5H10) 1b, C2Me4 1c), [Nb{(eta-(C5H3Bu)-Bu-t)C2Me4(eta-(C5H3Bu)-Bu-t)}Cl-2] 1d, [Nb{(eta-C5H4)X(eta-C5H4)}(eta(2)-BH4)] (X = CEt2 2a*, C(C5H10) 2b, C2Me4 2c*, SiMe2 2e*), [Nb((eta-(C5H3Bu)-Bu-t)C2Me4(eta-(C5H3Bu)-Bu-t)}(eta(2)-BH4)] (2d*), [Nb{(eta-C5H4)X(eta-C5H4)}(eta(2)-BD4)] (X = C2Me4 3c, CMe2 4), and [V{(eta-C5H4)C2Me4(eta-C5H4)}(eta(2)-BH4)} (5*) have been prepared. The asterisk indicates the crystal structure has been d...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/om990810n

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Institution:
University of Oxford
Oxford college:
Jesus College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
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Institution:
University of Oxford
Oxford college:
St John's College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Oxford college:
St Catherine's College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Chemical Crystallography Laboratory
Role:
Author
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Funding agency for:
Linda H. Doerrer
Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Volume:
19
Issue:
4
Pages:
630-637
Publication date:
2000-01-01
DOI:
ISSN:
0276-7333
URN:
uuid:81d4950b-09db-4a96-96d4-4e06e81d1c07
Local pid:
ora:2672

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