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Rotationally resolved zero-kinetic-energy photoelectron spectrum of nitrogen

Abstract:

Rotationally resolved zero-kinetic-energy (ZEKE) photoelectron spectra of the X^2 Σ_(g)^(+) (V^(+) = 0,1)← X^(1)Σ_(g)^(+) (v=0) bands of nitrogen have been recorded. The spectra show unexpected rotational-line intensities. The intensity distortions are explained by channel interactions. The strong S and U branches [N^(+) 0 J^(primeprime)) = +2 and +4, respectively] of the (1-0) band borrow intensity from a nearly degenerate Rydberg state, converging to an electronic excited state of the ion, ...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1103/PhysRevA.46.302

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Institution:
University of Cambridge
Department:
Department of Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Physical and Theoretical Chemistry Laboratory
Role:
Author
Royal Society More from this funder
Publisher:
American Physical Society Publisher's website
Journal:
Physical Review A Journal website
Volume:
46
Issue:
1
Pages:
302-314
Publication date:
1992-07-05
DOI:
EISSN:
1094-1622
ISSN:
1050-2947
URN:
uuid:801b37c3-ce76-4b7c-8a0f-baced0ddd661
Local pid:
ora:2898

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